Heat and mass transfer correlations for steam methane reforming. This type of reforming is also often referred to as autothermal reforming. A good catalyst design will have a low pressure drop to save on operating costs and have a high conversion. In particular, we point our attention mainly toward the influence of the different retentate and permeate flux configurations on both methane conversion and hydrogen recovery. The temperature in the tubes evolves from 675 to 1,000 k. Study of different designs of methanol steam reformers. The thesis studies the simulation, optimization and control structure design using stepwise approach of skogestad. The main, and most widespread, reactor designs for. Page 1 steam reforming of natural gas at petroleum refining facilities is the predominant means of producing hydrogen in the chemical process industries cpi. The main plant module, contains 9 reforming reactors, 10 combustors and 11 heat exchangers in a single integrated block.
In a mixed poxsr reformer system reactor the oxidation and steam reforming reactions all take place in the same reactor. Ngr are steam methane reforming smr and autothermal reforming atr. Finally, it is represented an approach of the total cost of the reactor, according to the design characteristics and the materials that can be used for its construction. It is a large scale operation carried out in rows of tubular reactors inserted into a gasfired furnace. Water enters the furnace, producing steam at a very high temperature. This invention in some embodiments relates to a chemical reactor design system in which a new method of electrical heating is disclosed to permit the reactor to operate as a high temperature gasification reactor, specifically steam co 2 reactor reforming, to achieve the very high temperatures needed without the use of combustion or oxygenblown. Design and evaluation of heat utilization systems for.
Comprehensive study of steam reforming of methane in. The main purpose of this technology is hydrogen production. Steam reforming free download as powerpoint presentation. Kinetics study and modelling of steam methane reforming. Jaeri has been conducting several studies to develop a framework of the httrsteam reforming system.
The configuration of this module, incorporating mab. The model describes mass and thermal dispersions for gas and solid phases. Schematic representation of steam reformer sr, membrane reactor mr. Conceptual design of a hydrogen production system by dme steam reforming and highefficiency nuclear reactor technology kimichika fukushima 1 and takashi ogawa2 1 toshiba corporation, 8, shinsugitacho, isogoku, yokohama 2358523 japan 2 toshiba corporation, 1, toshibacho, fuchu, tokyo 1838511 japan. Advanced modelling and optimisation of natural gas. Third, a highly endothermic reaction has the advantage that if the reactor should lose its heat transfer fluid, it would selfquench. If the kinetics of steam reforming could be greatly accelerated, a steam reformer reactor. This physical modeling will be used in a lumped parameter model of the steady state operation of the reactor. Subsequently, we design and evaluate three different feedback control schemes to drive the areaweighted average hydrogen mole fraction measured at the reforming tube outlet. These models were used to simulate smallscale reactors which generate the hydrogen consumed in a stack of htpemfc. Catalyst design influences process variables such as pressure drop, conversion, and heat transfer. Steam reforming of methane for production of hydrogen and.
Pdf design of steam reforming reactor for converting. The two main reformers, the steam methane reformer smr and the autothermal reformer atr were modelled. The kinetics of methane steam reforming over a niaal2o catalyst kaihu hou, ronald hughes. Because hydrogen needs within various sectors of the cpi are at their highest levels in history, and are continuing to grow, an understanding of this method of hydrogen production and purification can be useful. Design of process plant for producing hydrogen from steam. Methane steam reforming reaction behaviour in a packed. First in section 2 the design of a tubular reforming reactor will be explained. Methane steam reforming reaction in a labscale reactor. Hydrogen from natural gas via steam methane reforming smr.
A compact steam methane reforming smr reactor for h 2 production from natural gas was investigated using a steadystate threedimensional 3d computational fluid dynamics cfd model with heat transfer and chemical reactions. Cost and performance comparison of stationary hydrogen. Equipment design and cost estimation for small modular. Advanced modelling and optimisation of natural gas reforming. The 48% of current hydrogen production is via steam reforming of natural gas. On this research, a ru catalytic wall reactor was prepared to conduct kinetic measurements of the methane steam reforming at low temperatures from 573 to 723 k, and then a microkinetic. The kinetics of methane steam reforming over a ni o catalyst.
The aim of this study was to design and test labscale methanol steam reformers, and to employ the results of the experiments to develop a kinetic model for a new catalyst for methanol steam reforming at different conditions. Steam reforming or steam methane reforming is a method for producing syngas hydrogen and carbon monoxide by reaction of hydrocarbons with water. Methane steam reforming, methanation and watergas shift. Steam reforming is a highly endothermic process which is carried out by passing a mixture of steam and natural gas over a catalyst 16. Reactor design limitations for the steam reforming of methanol. Benchscale steam reforming of methane for hydrogen. The paper will examine the possibilities of co2 capture in a steam reforming based plant, and its impact on the economics of hydrogen production. The commercial steam methane reforming process is divided in two stages.
Steam reforming on nickelalumina catalysts is the main pro cess for the production of hydrogen or synthesis gas. Microkinetic analysis of the methane steam reforming on a. Reactor design abstract the zoneflow reactor tribute creations, llc is a tubular reactor with two types of internals. Subsequently the modeling of the chemical reactions in, and of the heat transfer to the reactor tubes, will be discussed in section 3. Computational fluid dynamics in chemical reactor analysis. In the steam reforming of naphtha avg formula c11h24 im considering to add a prereformer to first reduce the heavy hydrocarbons to methane and then use a membrane reactor to convert the. Instrinsic kinetics, diffusional influences, and reactor design, acs symp. Comparison of catalyst geometries for methane steam. The steam reforming hydrogen plant for many years, steam methane reforming smr has been the leading technology for generation of hydrogen in refining and petrochemical complexes. The hydrogen moves through the plant, while the oxygen joins carbon monoxide from the furnace reforming reaction and becomes. Control structure design for methanol process ntnu. Model for steam reforming of ethanol using a catalytic wall reactor j.
Pdf design of steam reforming reactor for converting methanol into hydrogen using an ultrasonic nebulizer as liquid feeder and polymer liquid processed cuoznoal2o3 particles as catalyst khairurrijal khairurrijal academia. Steam reacts with natural gas, producing hydrogen and carbon monoxide. Model for steam reforming of ethanol using a catalytic. The reaction is strongly endothermic consumes heat. Chapter 1 introduction this thesis presents a master of science degree project conducted at the department of chemical engineering, at ntnu. Steam reforming is a method for generating hydrogen by. These data points for ni and rh catalyst were plotted against the model to see how well the simulation predicted the experimental results. Design and optimization of a fixed bed reactor for. The feed materials natural gas, liquid gas or naphtha are endothermically converted with water steam into synthesis gas in catalytic tube reactors. Request pdf reactor design limitations for the steam reforming of methanol in this paper the limiting mechanisms in the methanolsteam reformation process. Equipment design and cost estimation for small modular biomass systems, synthesis gas cleanup, and oxygen separation equipment. Steam reforming is the most widespread process for the generation of hydrogenrich synthesis gas from light carbohydrates. The steam methane reforming process can be broken down into five distinct steps.
Steam reforming of natural gas the most economical and highly preferable process with the resources of eritrea is steam reforming of natural gas. A 2d model and heat transfer mechanism are proposed to analyze and study oxidative steam reforming of methane osrm in a membrane reactor. The endothermic reaction makes the steam reforming reactor a safer reactor. The effects of operating parameters on methane conversion and h 2 yield are. The two processes applied to generate h 2 from methanol are steam reforming and mixed partial oxidation pox steam reforming sr. Kinetics, catalysis and mechanism of methane steam reforming. The methane steam reforming reaction has been investigated from a modeling point of view, considering the effect of different parameters on methane conversion.
Water gas shift reactor additional hydrogen is created in the water gas shift reactor. Green, efficient, and economic energy conversion from methane steam reforming requires understanding the reaction mechanism and intensification of reactor design to better convert energy at plant scale. However, the models especially of reactors like reformers, are not very reliable. Pdf basic design of tubular steam reformer chathura. Methane steam reforming an overview sciencedirect topics. Hydrogen production via steam reforming with co2 capture. Scaleable, microstructured plant for steam reforming of. The fluidized bed steam reforming fbsr of nuclear waste is a relatively new technology, though the fluidization phenomenon and steam reforming are well established in the chemical engineering field.
The water gas shift reactor is filled with an ironchrome based catalyst that causes steam h 2o to break into oxygen and hydrogen. It also accounts for transport through the membrane. In order to study the technical feasibility of such a design, numerical simulations and modeling are used to investigate the strong endothermic reactions of methane steam reforming inside a microchannel reactor with palladium catalyst. In the water shift reactor, carbon monoxide and steam react to form carbon dioxide and more hydrogen gas. The smr reactor consisted of two main individual streams including combustion gas for reaction heat supply, and.
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